摘要:Aims. We investigated the possibility of diagnosing the degree of departure from the Maxwellian distribution using the Fe XVII–Fe XVIIIspectra originating in plasmas in collisional ionization equilibrium, such as in the cores of solar active regions or microflares.Methods. The original collision strengths for excitation are integrated over the non-Maxwellian electronκ-distributions characterized by a high-energy tail. Synthetic X-ray emission line spectra were calculated for a range of temperatures andκ. We focus on the 6–24 Å spectral range to be observed by the upcoming Marshall Grazing-Incidence X-ray Spectrometer MaGIXS.Results. We find that many line intensity ratios are sensitive to bothTandκ. Best diagnostic options are provided if a ratio involving both Fe XVIIand Fe XVIIIis combined with another ratio involving lines formed within a single ion. The sensitivity of such diagnostics toκis typically a few tens of per cent. Much larger sensitivity, of about a factor of two to three, can be obtained if the Fe XVIII93.93 Å line observed by SDO/AIA is used in conjuction with the X-ray lines.Conclusions. We conclude that the MaGIXS instrument is well-suited for detection of departures from the Maxwellian distribution, especially in active region cores.