文章基本信息

标题：Effect of transition metal ions on luminescence of MOFs
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作者：Bo Ruan ; Huan-Li Liu ; Xue-Qing Zhan 等
期刊名称：MATEC Web of Conferences
电子版ISSN：2261-236X
出版年度：2018
卷号：238
DOI：10.1051/matecconf/201823805004
语种：English
出版社：EDP Sciences
摘要：Three kinds of metal-organic framework materials (MOF-5, MLI-101(Cr), UiO-66) are synthesized, which are based on transition metal (Zn, Cr, Zr) as the center ions, and terephthalic acid (H2BDC) as organic ligand. At the same time, three kinds of MOFs were characterized and analyzed with X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-visible absorption spectrometer (UV-Vis), and fluorescence spectrometer (PL). This article analyzes the fluorescence effects of these three MOFs and investigates the role of different transition metal ions in MOF luminescence. The results show that the ionic radii of Zn2 +and Zr4 +are similar, which are 0.074 nm and 0.072 nm, respectively. MOF-5 and UiO-66 have similar fluorescence effects, both of which emit blue-violet light. However, MIL-101 (Cr) fluorescence centers on Cr3 +with an ionic radius of 0.0651 nm emits yellow-green light, which is different from the foregoing MOFs. Therefore, the ionic radius of the transition metal has an important effect on the fluorescence effect of the MOF. For larger ionic radii, the fluorescence of MOF is generally in the blue-violet square region.