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标题：Photochemical of Polychlorinated biphenyl by the photolysis and solvent
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作者：Hassan Asilian ; Reza Gholamnia ; Abbass Rezaee 等
期刊名称：Journal of Applied Sciences and Environmental Management
印刷版ISSN：1119-8362
出版年度：2010
卷号：14
期号：4
DOI：10.4314/jasem.v14i4.63281
语种：English
出版社：Department of Pure & Industrial Chemistry, University of Port Harcourt
摘要：Polychlorinated biphenyls (PCBs) are one group of persistent organic pollutants (POPs) that are of international concern because of global distribution, persistence, and toxicity. Removal of these compounds from the environment remains a very difficult challenge because the compounds are highly hydrophobic and have very low solubility in water. The photochemical reactor was of annular geometry with a cylindrical low-pressure mercury lamp. The whole Lamp was immersed in a reactor thermostat controlling the temperature at 32 ± 2 °C. The Polychlorinated biphenyls (PCBs) were analyzed by GC/ECD. The degradation of PCBs in terms of one, two and three lamp was 91.9%, 92.7% and 93% respectively. The degradation of PCBs in terms of use of 10% and 20% of total volume of solution of H 2 O 2 were 88.8% and 93% respectively. The degradation of PCBs in terms of ratio to ethanol with oil transformer in 1:1, 2:1 and 3:1 was 83.4%, 92.5% and 93% respectively. The experiments show that UVC-photolysis of H 2 O 2 leads to a degradation efficiency of PCBs in the presence of ethanol. @ JASEM J. Appl. Sci. Environ. Manage . December, 2010, Vol. 14 (4) 107 - 112