文章基本信息

标题：A Great Achievement of Calculated and Experimental Results of Char Kinetic Rate in Woody Mahogany Pyrolysis
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作者：Widya Wijayanti ; Mega Nur Sasongko
期刊名称：MATEC Web of Conferences
电子版ISSN：2261-236X
出版年度：2018
卷号：159
DOI：10.1051/matecconf/201815902046
语种：English
出版社：EDP Sciences
摘要：In the pyrolysis process, it is needed to know the value ofk(rate costant) to know the rate of reaction that occurs. It is needed to calculate k caused byTeffect due to the reason that it is extremely difficult experimentally to find rate constants. The pyrolysis process was carried out for three hours with the minimum condition of Oxygen using mahogany wood. It was used the pyrolysis temperature variations of 250°C to 800°C. The results showed the increasing temperature and decreasing mass of char as long as the process to obtain, the kinetic rate of chark. We used two calculation approaches method to find the calc ulatedk. Fristly, it used the total kinetic rate model equation with the equationkT=60.3 e-2028.4/Tand the second one, it was used the local kinetic rate model. In the local kinetic rate approached, it was divided the 3 temperature ranges;k1in the range of 28°C - 250°C wask1=539.1 e-2907.3/T,k2in the range of 250°C to 500°C wask2=27.11 e-1424/T; andk3in the range of at range 500°C to 800°C wask3=572.4 e-4549.2/T. Then, by using the foundkvalues, it was found the great achievement results that the decreasing mass of char in the calculation was coincide with the experimental results. It was used both kinetic rate methods depending on the required energy was needed in the pyrolysis process; at low pyrolysis temperatures, the appropriate kinetic rate model was a local kinetic rate model, and for pyrolysis at high temperatures of 600°C to 800°C, the accurate kinetic rate model was the total kinetic rate model.