文章基本信息

标题：Reaction flux versus reaction force: easy to stabilize?
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作者：N. Ha Hoang ; Denis Dochain ; Nicolas Hudon 等
期刊名称：IFAC PapersOnLine
印刷版ISSN：2405-8963
出版年度：2017
卷号：50
期号：1
页码：558-563
DOI：10.1016/j.ifacol.2017.08.072
语种：English
出版社：Elsevier
摘要：AbstractChemical reaction rate, also known as the reaction flux involved in chemical reactors, plays a central role as the source generating the abnormal dynamics characteristics. This paper proposes a structural approach for the stabilization of such systems through the control of the reaction flux by considering the Lyapunov stability theory within a standard thermodynamic framework. More precisely, the reaction flux is structurally considered as a nonlinear function of conjugated reaction force. The thermodynamic constraint of such a relationship is that the inherent non-negative definiteness property of the irreversible entropy production due to chemical reaction has to be fulfilled. Consequently, it allows to reexpress a large class of reaction rates described by the mass-action-law and more interestingly, the operation of the reaction system at a desired set-point consists in controlling the reaction force on the basis of an affinity-related storage function. Numerical simulations for a non isothermal continuous stirred tank reactor (CSTR) involving one reversible reaction operated with multiple steady states illustrate the application of the theoretical developments.
关键词：KeywordsLyapunov functionthermodynamicsaffinityentropy productionCSTR