文章基本信息

标题：Preparation of high quality Microgranulate CrO3 based on green process design
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作者：Wenwen Cui ; Wenwen Cui ; Ping Li 等
期刊名称：Canadian Journal of Chemical Engineering
印刷版ISSN：0008-4034
出版年度：2017
卷号：95
期号：7
页码：1261-1268
DOI：10.1002/cjce.22764
语种：English
出版社：Chemical Institute of Canada
摘要：Abstract A mild crystallization process was proposed to prepare chromium trioxide (CrO3) by reaction between K2Cr2O7 and HNO3 aqueous solutions. Through ICP, XRPD, SEM, and EDS analysis, key factors and mechanisms that influenced the preparation of CrO3 were studied. Large spherical particles of CrO3 (d50 ≥ 300 µm) with high purity (CrO3 ≥ 0.99 g/g, K ≤ 2 mg/g) were prepared when the initial concentration of K2Cr2O7 was kept at 80 g/100 mL HNO3, the acid feeding rate and the cooling rate were set at 1 mL · min−1 and 0.1 °C · min−1, respectively, and the direct recovery of Cr6+ was up to more than 95 %. Kinetic analysis indicated that low nucleation rate and high growth rate would favour the increase of CrO3 particle size in this process. As a high‐valued byproduct, Cr(VI)‐free KNO3 was further prepared with the designed crystallization steps. Additionally, green characteristics of the process were also discussed. A mild crystallization process was proposed to prepare chromium trioxide (CrO3). Key factors and mechanism that influenced preparation of CrO3 were studied. Kinetic analysis was performed, and green characteristics of the process were also discussed.
关键词：enchromium trioxide (CrO3)particle sizepuritykineticgreen process