文章基本信息

标题：Chemical Shifts of Kα and Kβ1,3 X-ray Emission Spectra for Oxygen Compounds of Ti, Cr, Fe, Co, Cu with WDXRF
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作者：E. Boydaş ; E. Boydaş ; E. Orhan 等
期刊名称：Procedia - Social and Behavioral Sciences
印刷版ISSN：1877-0428
出版年度：2015
卷号：195
页码：1757-1761
DOI：10.1016/j.sbspro.2015.06.327
语种：English
出版社：Elsevier
摘要：Chemical shifts and full widths at half maximum intensity (FWHM) of Kα and Kβ1,3 x-ray emission lines and differences of full widths at half maximum intensity (ΔFHWM) using metallic element as reference for these emission lines were measured for oxygen compounds of elements in the range 22 ≤ Z ≤ 29 with a Wavelength-Dispersive X-Ray Fluorescence spectrometry (WDXRF). It was also found larger chemical shifts and FWHM for Kβ1,3 lines than those of Kα ones. It should be noted that the magnitude of chemical shifts increases with increase in the numbers of ligand atom.
关键词：Chemical shifts;ligand atom;FWHM ;