文章基本信息

标题：A phenomenological model for improving understanding of the ammonium nitrate agglomeration process
本地全文：下载
作者：Alvaro Videla Leiva ; Alvaro Videla Leiva ; Catalina Polanco Palacios 等
期刊名称：E3S Web of Conferences
印刷版ISSN：2267-1242
电子版ISSN：2267-1242
出版年度：2016
卷号：8
页码：1-1
DOI：10.1051/e3sconf/20160801067
语种：English
出版社：EDP Sciences
摘要：Ammonium nitrate is intensively used as explosive in the mining industry as the main component of ANFO. The ammonium nitrate is known to be a strong hygroscopic crystal matter which generates problems due to the creation of water bridges between crystals leading later to nucleation and crystallization forming an agglomerated solid cake. The agglomeration process damages the ammonium nitrate performance and is undesirable. Usually either organic or inorganic coatings are used to control agglomeration. In the present work a characterization method of humidity adsorption of the ammonium nitrate crystal was performed under laboratory conditions. Several samples were exposed into a defined humidity in a controlled chamber during 5 hours after which the samples were tested to measure agglomeration as the resistance force to compression. A clear relation was found between coating protection level, humidity and agglomeration. Agglomeration can be then predicted by a phenomenological model based of combination of the mono-layer BET adsorption and CNT nucleation models.