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标题：Thermodynamic properties of binary liquid systems of ethanoic acid, propanoic acid, and butanoic acid with 3-chloroaniline as a function of various temperatures
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作者：D. Rahul ; D. Rahul ; M. Gowri Sankar 等
期刊名称：Karbala International Journal of Modern Science
印刷版ISSN：2405-609X
电子版ISSN：2405-609X
出版年度：2016
卷号：2
期号：2
页码：78-87
DOI：10.1016/j.kijoms.2016.02.001
语种：English
出版社：Elsevier
摘要：Abstract The densities (ρ) and viscosities (η) are reported for binary mixtures of 3-chloroaniline with carboxylic acids such as ethanoic acid, propionic acid and butanoic acid over the entire range of mole fractions at T = (303.15–318.15) K and at constant atmospheric pressure. The excess properties such as excess volume and deviation in viscosity are calculated from the density and viscosity data. Excess properties are correlated by the Redlich–Kister equation. The variations of these properties with the composition of binary mixtures suggest the loss of dipolar association, difference in size and shape of the component molecules, dipole–dipole interactions and hydrogen bonding between unlike molecules. Graphical abstract Display Omitted
关键词：Density;Viscosity;3-Chloroaniline;Carboxylic acids